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What is the systematic name for [Ru(NH3) 2(en) ](NO3) 2?


A) (ethylenediamine) diammineruthenium(II) nitrate
B) diamminebis(ethylenediamine) ruthenium(III) nitrate
C) diammine(ethylenediamine) ruthenium(II) nitrate
D) diammine(ethylenediamine) nitratoruthenium(III)
E) bis(ethylene) diamminenitratoruthenate(II)

F) C) and D)
G) C) and E)

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In the complex ion [Cr(C2O4) 2(H2O) 2]-,what is the oxidation number of Cr?


A) +1
B) +2
C) +3
D) -2
E) -1

F) A) and E)
G) C) and D)

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What is the electron configuration of a ground-state Ag atom?


A) [Kr]5s14d10
B) [Kr]5s15d10
C) [Kr]5s24d9
D) [Kr]5s25d9
E) [Kr]5d10

F) C) and E)
G) A) and E)

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Which of the following ions could exist in either the high-spin or low-spin state in an octahedral complex?


A) Sc3+
B) Ni2+
C) Mn2+
D) Ti4+
E) Zn2+

F) A) and D)
G) None of the above

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Write the formula for sodium tetracyanonickelate(II) .


A) Na[Ni(CN) 4]
B) Na[Ni(CN) 4]2
C) Na2[Ni(CN) 4]
D) Na4[Ni(CN) 4]
E) Na[(NiCN) 4]

F) C) and D)
G) A) and D)

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What geometry is particularly common for complexes of d10 metal ions?

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Which of the following will be paramagnetic?


A) V5+
B) Ni2+
C) Mn7+
D) Ti4+
E) Zn2+

F) A) and B)
G) A) and D)

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What is the label used for an isomer which is levorotatory?

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In the complex ion [Co(en) 2Br2]+,what is the oxidation number of Co?


A) +1
B) +2
C) +3
D) -2
E) -1

F) None of the above
G) A) and D)

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How many donor atoms enable EDTA to form a stable complex ion with lead?


A) 6
B) 2
C) 4
D) 3
E) 5

F) B) and C)
G) A) and E)

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What is the electron configuration of a ground-state Zn2+ ion?


A) 1s22s22p63s23p64s13d9
B) 1s22s22p63s23p64s14d9
C) 1s22s22p63s23p64s23d8
D) 1s22s22p63s23p64s24d8
E) 1s22s22p63s23p63d10

F) None of the above
G) B) and E)

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Which of the following ions could exist in only the high-spin state in an octahedral complex?


A) Cr2+
B) Mn4+
C) Fe3+
D) Co3+
E) Ni2+

F) A) and D)
G) All of the above

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Which statement is correct about transition metals?


A) They have incompletely filled d subshells.
B) They form ions with incompletely filled d subshells.
C) They form paramagnetic compounds.
D) They have catalytic activity.
E) All of the answers are correct.

F) C) and D)
G) A) and D)

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In the coordination compound [Cr(NH3) (en) 2Cl]Br2,the coordination number (C.N.) and oxidation number (O.N.) of the metal atom are,respectively,


A) C.N.= 6; O.N.= +4.
B) C.N.= 6; O.N.= +3.
C) C.N.= 5; O.N.= +2.
D) C.N.= 4; O.N.= +2.
E) C.N.= 4; O.N.= +3.

F) D) and E)
G) C) and E)

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The best name for K[Cr(NH3) 2Cl2(CN) 2] is


A) potassium diamminedichlorodicyanochromate(III) .
B) potassium diamminedichlorodicyanochromium(III) .
C) potassium diamminedichlorochromatium(III) cyanide.
D) potassium diamminedichlorochromate(II) cyanide.
E) potassium diamminedichlorodicyanochromate(II) .

F) All of the above
G) D) and E)

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If a solution absorbs green light,what is its likely color?


A) Red
B) Violet
C) Orange
D) Yellow
E) Blue

F) A) and E)
G) All of the above

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The atom in a ligand that is bound directly to the metal atom is known as the ______ _______.

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What is the electron configuration of a ground-state Fe2+ ion?


A) [Ar]3d5
B) [Ar]4s13d5
C) [Ar]3d6
D) [Ar]4s14d5
E) [Ar]4d6

F) B) and D)
G) B) and C)

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What is the systematic name for Cr(CO) 3(NH3) 3?


A) chromiumtriaminotricarbonyl
B) triamminechromium carbonate
C) triamminetricarbonylchromate(0)
D) triamminetricarbonylchromium(0)
E) tris(amino) tris(carbonyl) chromium

F) A) and E)
G) A) and B)

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The numbers of geometrical isomers and optical isomers of the complex ion [Co(en) 3]3+ are,respectively,


A) 2 and 2.
B) 1 and 1.
C) 3 and 2.
D) 1 and 2.
E) 2 and 4.

F) All of the above
G) A) and E)

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